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Discovery of a novel, large pore phase in a bimetallic Al/V metal-organic framework

Tijdschriftbijdrage - Tijdschriftartikel

A new series of bimetallic COMOC-2(V)/DUT-5(Al) frameworks are developed and fully characterized. Electron paramagnetic resonance and transmission electron microscopy confirm the homogeneous dispersion of Al/V in the entire framework. The study of the flexibility by means of CO2 pressure dependent XRPD and high pressure sorption reveals the co-existence of two different large pore phases and a narrow pore phase in the entire pressure regime.
Tijdschrift: JOURNAL OF MATERIALS CHEMISTRY A
ISSN: 2050-7496
Issue: 47
Volume: 5
Pagina's: 24580 - 24584
Jaar van publicatie:2017
BOF-keylabel:ja
IOF-keylabel:ja
BOF-publication weight:10
CSS-citation score:1
Auteurs:National
Authors from:Higher Education
Toegankelijkheid:Closed