The first 4d/4f single-molecule magnet containing a {(Ru2Dy2III)-Dy-III} core

We report the synthesis, structure and magnetic properties of the first 4d-4f single-molecule magnet. The complex [Ru(III)2Dy(III)2(OMe)2(O2CPh)4(mdea)2(NO3)2] displays a butterfly type core, with an anisotropy barrier of 10.7 cm(-1). Ab initio and DFT calculations provide insight into the observed magnetic behaviour.

Jaar van publicatie:2015

BOF-keylabel:ja

IOF-keylabel:ja

BOF-publication weight:2

CSS-citation score:1

Auteurs:International

Authors from:Higher Education