Low‐Dimensional Hybrid Perovskites Containing an Organic Cation with an Extended Conjugated System: Tuning the Excitonic Absorption Features

Low‐dimensional hybrid perovskites are receiving increased attention. One of the advantages of the low‐dimensional hybrids over their 3D counterparts is their greater structural flexibility towards the incorporation of bigger, more complex, organic cations. In this communication, we introduce a pyrene derivative as an organic cation containing an extended π‐system for use in a variety of low‐dimensional hybrids. We show that materials with different excitonic absorption features can be obtained by tuning the iodide/lead ratio in the precursor solutions, using the same pyrene cation. In this way, hybrids with optical characteristics corresponding to 2D, 1D and 0D hybrid perovskites are obtained. The formation and thermal stability of the different hybrids is analysed and compared.

Jaar van publicatie:2019

Trefwoorden:excitons, low-dimensional, organic-inorganic hybrid composites, perovskite phases, stability

BOF-keylabel:ja

IOF-keylabel:ja

BOF-publication weight:1

CSS-citation score:1

Authors from:Government, Higher Education, Private

Toegankelijkheid:Closed